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Determination of the Relative Oxidative Stability of Polyethylene Bottle Tops by Differential Scanning Calorimetry (DSC)

Oxidative degradation of polymers is an exothermic process (releases heat) and is detectable by differential scanning calorimetry (DSC). Furthermore, DSC evaluation of polyethylene at elevated temperatures in the presence of oxygen is an effective method for accelerating the onset of degradation so that longer term (shelf life) properties can be predicted and/or compared.

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DSC Step Annealing for Fingerprinting Molecular Structure in Poly(vinylidene fluoride)

DSC step annealing is used to study the fine molecular structure of poly(vinylidene fluoride) (PVDF) homopolymers and copolymers. The melting pattern, obtained after step annealing, is a characteristic “fingerprint” for small variations in structure. This “fingerprint” detects variations in the polymerization process, the molecular weight of the polymer, the fraction and the nature of the co-monomer.

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